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DIVISION: I&C NEW PRODUCTS DEPARTMENT TRADE NAME: NEXTEL(tm) 440 CERAMIC FIBER WITH 299 or 399 TYPE SIZING ID NUMBER/U.P.C.: 98-0400-0248-1 - - - 98-0400-0249-9 - - - 98-0400-0260-6 - - - 98-0400-0265-5 - - - 98-0400-0266-3 00-51115-00261-8 98-0400-0328-1 00-51115-00300-4 98-0400-0360-4 - - - 98-0400-0361-2 - - - 98-0400-0362-0 - - - 98-0400-0372-9 - - - 98-0400-0378-6 00-51115-00335-6 98-0400-0390-1 - - - 98-0400-0402-4 00-51115-00655-5 98-0400-0430-5 00-51115-00678-4 98-0400-0523-7 00-51115-02450-4 98-0400-0526-0 00-51115-02453-5 98-0400-0527-8 00-51115-02454-2 98-0400-0535-1 - - - 98-0400-0539-3 00-51115-02458-0 98-0400-0542-7 00-51115-02460-3 98-0400-0546-8 00-51115-02463-4 98-0400-0547-6 00-51115-02464-1 98-0400-0548-4 - - - 98-0400-0558-3 - - - 98-0400-0561-7 00-51115-02474-0 98-0400-0566-6 00-51115-02477-1 98-0400-0569-0 - - - 98-0400-0576-5 - - - 98-0400-0578-1 00-51115-02486-3 98-0400-0582-3 00-51115-02490-0 98-0400-0591-4 00-51115-02492-4 98-0400-0592-2 00-51115-02493-1 98-0400-0602-9 00-51115-02648-5 98-0400-0603-7 00-51115-02649-2 98-0400-0606-0 00-51115-02652-2 98-0400-0639-1 00-51115-02668-3 98-0400-0645-8 - - - 98-0400-0646-6 - - - 98-0400-0647-4 - - - 98-0400-0648-2 00-51115-02670-6 98-0400-0649-0 00-51115-02671-3 98-0400-0650-8 00-51115-02672-0 98-0400-0651-6 00-51115-02673-7 98-0400-0652-4 00-51115-02675-1 98-0400-0653-2 00-51115-02674-4 98-0400-0663-1 00-51115-02678-2 98-0400-0671-4 00-51115-02682-9 98-0400-0692-0 00-51115-02696-6 98-0400-0699-5 00-51115-03253-0 98-0400-0701-9 00-51115-03255-4 98-0400-0711-8 00-51115-03262-2 98-0400-0725-8 00-51115-03273-8 98-0400-0794-4 00-51115-03329-2 98-0400-0795-1 00-51115-03330-8 98-0400-0869-4 00-51115-03337-7 98-0400-0894-2 00-51115-03348-3 98-0400-0909-8 00-51115-03757-3 98-0400-0932-0 00-51115-03771-9 98-0400-0933-8 00-51115-03772-6 98-0400-0998-1 00-51115-03795-5 98-0400-1027-8 00-51115-03815-0 98-0400-1028-6 00-51115-03816-7 98-0400-1040-1 - - - 98-0400-1042-7 00-51115-03828-0 98-0400-1115-1 00-51115-03838-9 98-0400-1123-5 00-51115-03844-0 98-0400-1279-5 00-51115-03954-6 98-0400-1427-0 00-51115-03991-1 98-0400-1436-1 00-51115-03999-7 98-0400-1564-0 00-51115-04389-5 98-0400-1772-9 00-51115-04458-8 98-0400-1773-7 00-51115-04457-1 98-0400-1893-3 00-51115-04564-6 98-0400-1895-8 00-51115-04566-0 98-0400-2186-1 - - - 98-0400-2187-9 - - - ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: NEXTEL(tm) 440 CERAMIC FIBER WITH 299 or 399 TYPE SIZING May 04, 2000 PAGE 2 ----------------------------------------------------------------------------- HEADING (continued) ----------------------------------------------------------------------------- 98-0400-2188-7 - - - 98-0400-2189-5 - - - 98-0400-2190-3 - - - 98-0400-2191-1 - - - 98-0400-2195-2 - - - 98-0400-2196-0 - - - 98-0400-2197-8 - - - 98-0400-2207-5 - - - 98-0400-2208-3 - - - 98-0400-2209-1 - - - 98-0400-2210-9 - - - 98-0400-2230-7 00-51115-07142-3 98-0400-2266-1 - - - 98-0400-2450-1 00-51115-07265-9 98-0400-5920-0 00-51115-09668-6 98-0400-5921-8 00-51115-09669-3 98-0400-5922-6 00-51115-09670-9 ISSUED: May 04, 2000 SUPERSEDES: March 08, 1999 DOCUMENT: 10-4881-8 ----------------------------------------------------------------------------- 1. INGREDIENT C.A.S. NO. PERCENT ----------------------------------------------------------------------------- ALUMINOBOROSILICATE FIBERS.............. 12788-79-3 96.5 - 99.5 ORGANIC SIZING.......................... Unknown 0.5 - 3.5 ----------------------------------------------------------------------------- 2. PHYSICAL DATA ----------------------------------------------------------------------------- BOILING POINT:................. N/A VAPOR PRESSURE:................ N/A VAPOR DENSITY:................. N/A EVAPORATION RATE:.............. N/A SOLUBILITY IN WATER:........... 0.5 - 3.5 % SPECIFIC GRAVITY:.............. 3.05 Water=1 PERCENT VOLATILE:.............. 0.5 - 3.5 % by wt pH:............................ N/A VISCOSITY:..................... SOLID MELTING POINT:................. > 1800 C APPEARANCE AND ODOR: Textile grade (greater than 7 microns in diameter) shiny, white, odorless, thread, yarn or fabric. ----------------------------------------------------------------------------- 3. FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------- FLASH POINT:................... N/A FLAMMABLE LIMITS - LEL:........ N/A FLAMMABLE LIMITS - UEL:........ N/A AUTOIGNITION TEMPERATURE:...... N/A ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: NEXTEL(tm) 440 CERAMIC FIBER WITH 299 or 399 TYPE SIZING May 04, 2000 PAGE 3 ----------------------------------------------------------------------------- 3. FIRE AND EXPLOSION HAZARD DATA (continued) ----------------------------------------------------------------------------- EXTINGUISHING MEDIA: Not applicable SPECIAL FIRE FIGHTING PROCEDURES: None known. UNUSUAL FIRE AND EXPLOSION HAZARDS: None known. NFPA HAZARD CODES: HEALTH: 0 FIRE: 1 REACTIVITY: 0 UNUSUAL REACTION HAZARD: none ----------------------------------------------------------------------------- 4. REACTIVITY DATA ----------------------------------------------------------------------------- STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: None known. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide Formic acid and trace amounts of other substances. ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE: Observe precautions from other sections. Vacuum, use wet sweeping compound or water to avoid dusting. CAUTION! A vacuum cleaner could be an ignition source. Place in an approved metal container. RECOMMENDED DISPOSAL: Dispose of waste product in a sanitary landfill. Reclaim if feasible. ENVIRONMENTAL DATA: Not determined. REGULATORY INFORMATION: Volatile Organic Compounds: N/D. VOC Less H2O & Exempt Solvents: N/D. Since regulations vary, consult applicable regulations or authorities ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: NEXTEL(tm) 440 CERAMIC FIBER WITH 299 or 399 TYPE SIZING May 04, 2000 PAGE 4 ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION (continued) ----------------------------------------------------------------------------- before disposal. U.S. EPA Hazardous Waste Number = None (Not U.S. EPA Hazardous). EPCRA HAZARD CLASS: FIRE HAZARD: No PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: No ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID ----------------------------------------------------------------------------- EYE CONTACT: Immediately flush eyes with large amounts of water. Get immediate medical attention. SKIN CONTACT: Flush skin with large amounts of water. If irritation persists, get medical attention. INHALATION: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: No need for first aid is anticipated. ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION ----------------------------------------------------------------------------- EYE PROTECTION: Avoid eye contact. Wear safety glasses with side shields. SKIN PROTECTION: Avoid prolonged or repeated skin contact. Wear appropriate gloves when handling this material. Use one or more of the following personal protection items as necessary to prevent skin contact: coveralls. RECOMMENDED VENTILATION: Provide appropriate local exhaust when product is heated. Use in a well-ventilated area. Provide sufficient ventilation to maintain emissions below recommended exposure limits. If exhaust ventilation is not adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: Avoid breathing of airborne material. Avoid breathing of thermal decomposition products. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: half-mask dust respirator, full- face dust respirator. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: NEXTEL(tm) 440 CERAMIC FIBER WITH 299 or 399 TYPE SIZING May 04, 2000 PAGE 5 ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION (continued) ----------------------------------------------------------------------------- PREVENTION OF ACCIDENTAL INGESTION: Do not ingest. RECOMMENDED STORAGE: Keep out of the reach of children. FIRE AND EXPLOSION AVOIDANCE: Not applicable. EXPOSURE LIMITS INGREDIENT VALUE UNIT TYPE AUTH SKIN* ----------------------------------------------------------------------------- ALUMINOBOROSILICATE FIBERS........... 1.0 FIBER/CC TWA OSHA PROPOSED REFRACTORY CERAMIC FIBERS ALUMINOBOROSILICATE FIBERS........... 1.0 FIBER/CC TWA CMRG REFRACTORY CERAMIC FIBERS ORGANIC SIZING....................... NONE NONE NONE NONE * SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - CMRG: Chemical Manufacturer Recommended Exposure Guidelines - OSHA: Occupational Safety and Health Administration - NONE: None Established ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA ----------------------------------------------------------------------------- EYE CONTACT: Mechanical eye irritation: signs/symptoms can include irritation, redness, scratching of the cornea and tearing. SKIN CONTACT: Mechanical skin irritation: signs/symptoms can include itching and redness. INHALATION: Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. Vapors of heated material may cause respiratory system irritation. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: NEXTEL(tm) 440 CERAMIC FIBER WITH 299 or 399 TYPE SIZING May 04, 2000 PAGE 6 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA (continued) ----------------------------------------------------------------------------- IF SWALLOWED: Ingestion is not a likely route of exposure to this product. Irritation of Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood in feces. CANCER: WARNING: Contains a chemical which can cause cancer. (CERAMIC FIBERS) (IARC possible human carcinogen 2B, Calif. Proposition 65) Due to their large size, Nextel(TM) Ceramic Fibers are considered to be non-respirable and, therefore, unlikely to pose a cancer risk. Respirable fibers are defined by the World Health Organization as having lengths greater than 5 microns, diameters less than 3 microns and length-to-diameter ratios greater than 3:1. Nextel(TM) Ceramic Fibers have diameters of 7 to 13 microns and are continuous in length. ----------------------------------------------------------------------------- SECTION CHANGE DATES ----------------------------------------------------------------------------- HEADING SECTION CHANGED SINCE March 08, 1999 ISSUE INGREDIENTS SECTION CHANGED SINCE March 08, 1999 ISSUE REACTIVITY DATA SECTION CHANGED SINCE March 08, 1999 ISSUE PRECAUTIONARY INFO. SECTION CHANGED SINCE March 08, 1999 ISSUE HEALTH HAZARD DATA SECTION CHANGED SINCE March 08, 1999 ISSUE ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: NEXTEL(tm) 440 CERAMIC FIBER WITH 299 or 399 TYPE SIZING May 04, 2000 PAGE 7 ----------------------------------------------------------------------------- The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.